Pressure-induced electron transfer in cobalt-iron Prussian blue complex studied by RIXS
نویسندگان
چکیده
منابع مشابه
Formation of cobalt-Prussian Blue nanoparticles in a biopolymer matrix.
The molecular magnet material, cobalt-Prussian Blue, has been synthesized using chitosan as a morphological structure-directing agent. The strong chelating ability of the biopolymer ensures that the inorganic phase remains nanoparticulate. SQUID magnetometry reveals that the nanoparticles exhibit a sharp ferrimagnetic to paramagnetic transition at 16 K.
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Comparative reactivities of three diaqua(tetraamine)Co(III) complexes towards hydrolysis of 4-nitrophenyl phosphate was undertaken. The results were contrasted with prussian blue promoted hydrolysis of 4-nitrophenyl phosphate. The tetraamineCobalt(III) complexes accelerated the hydrolytic reaction to varying degrees with the following reactivity order. [(tn)2Co(OH2)2] < [(trpn)Co(OH2)2] < [(tme...
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A new morphology of Prussian blue microcrystals has been prepared by selective etching. By thermal decomposition, PB has been transformed into mesoporous magnetic iron(III) oxide.
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The ability of time-resolving enthalpy (∆H) and structural volume (∆V) changes in the nanoto μs time range offered by laser-induced optoacoustic spectroscopy (LIOAS) opens the possibility of a stepwise thermodynamic analysis of chromophore-medium interactions upon photoinduced reactions in biological systems. We applied LIOAS to biological photoreceptors, as well as to model systems, with the p...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section A Foundations of Crystallography
سال: 2005
ISSN: 0108-7673
DOI: 10.1107/s0108767305084138